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Beilstein J. Org. Chem. 2022, 18, 1203–1209, doi:10.3762/bjoc.18.125
Graphical Abstract
Scheme 1: a) Mechanochemical synthesis of g-PCN from sodium phosphide and trichlorotriazine (previous work [38]) ...
Figure 1: PXRD patterns of g-h-PCN (green) and g-h-PCN300 (teal).
Figure 2: XPS scans of a) C 1s, b) N 1s and c) P 2p for the pre-annealed g-h-PCN and d) C 1s, e) N 1s and f) ...
Figure 3: 31P MAS NMR of a) g-h-PCN and b) g-h-PCN300. Asterisks denote spinning sidebands.
Figure 4: Calculated structures for a) corrugated (edge facing), b) corrugated (single layer), c) layered g-h...